Ammonium polyphosphate CAS# 68333-79-9

Non-Toxic and Environmentally FriendlyHalogen-free and safe for use in various industrial and consumer applications.

Versatile Flame RetardantEffective in coatings, paints, plastics, textiles, and wood for fire protection.

High Thermal Stability (Phase II):Phase II APP decomposes above 300 °C, making it suitable for high-temperature applications.

Controlled Solubility and PolymerizationAvailable in two forms—Phase I (short-chain, water-sensitive) and Phase II (long-chain, low water solubility)—allowing tailored performance for specific needs.


Product Details

Ammonium Polyphosphate (APP) CAS#68333-79-9

Ammonium Polyphosphate (APP) is a non-toxic, halogen-free flame retardant derived from polyphosphoric acid and ammonia. It exists in two main types:

APP Phase I: Short, linear chains (n<100), water-sensitive, decomposes above 150 °C.

APP Phase II: High polymerization, branched structure (n>1000), thermally stable, decomposes above 300 °C, low water solubility, high-quality non-halogenated flame retardant.

Ammonium polyphosphate CAS# 68333-79-9

Ammonium polyphosphate Chemical Properties

density 1.74[at 20℃]
vapor pressure 0.076Pa at 20℃
storage temp. −20°C
solubility Aqueous Acid (Slightly)
form Solid
color White to Off-White
biological sourcerabbit
InChIInChI=1S/3H3N.H3O4P/c;;;1-5(2,3)4/h3*1H3;(H3,1,2,3,4)
InChIKeyZRIUUUJAJJNDSS-UHFFFAOYSA-N
SMILESP(=O)([O-])([O-])[O-].[N+]([H])([H])([H])[H].[N+]([H])([H])([H])[H].[N+]([H])([H])([H])[H]
LogP-2.148 (est)
CAS DataBase Reference68333-79-9
EPA Substance Registry SystemAmmonium polyphosphates (68333-79-9)

Safety Information

TSCA TSCA listed


Ammonium polyphosphate CAS# 68333-79-9

Product Application of Ammonium Polyphosphate CAS#68333-79-9

Ammonium Polyphosphate (APP) is an eco-friendly, halogen-free flame retardant widely used in coatings, paints, and engineering plastics. It serves as the main component in intumescent flame retardant systems and can be used alone or with other materials for flameproofing textiles, paper, fibers, and wood. High-concentration formulations (up to 50% P/N) are also available for specialized applications.

APP is also used in fertilizers, commonly with N-P₂O₅-K₂O ratios of 10-34-0 or 11-37-0. Polyphosphate fertilizers provide high nutrient content, good stability, and compatibility with other micronutrients, making them ideal for long-term storage and plant nutrition.

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Ammonium polyphosphate CAS# 68333-79-9

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