2,2'-Azobis(2-methylpropionitrile) CAS#78-67-1

  • Effective Radical Initiator: AIBN is widely used as a radical initiator in vinyl polymerizations and other chemical reactions.

  • Versatile Solubility: It is soluble in alcohols and many common organic solvents, allowing flexible use in various formulations.

  • Foaming and Blowing Agent: AIBN functions effectively as a foamer and blowing agent in plastics and rubber production.

  • High Reactivity for Industrial Applications: Its ability to ignite readily and burn persistently makes it suitable for catalytic and polymerization processes.


Product Details

Product Description of 2,2'-Azobis(2-methylpropionitrile) CAS#78-67-1

Azobisisobutyronitrile (AIBN, CAS#78-67-1) is an organic compound with the formula [(CH₃)₂C(CN)]₂N₂. It appears as a white powder that is soluble in alcohols and a wide range of common organic solvents, but insoluble in water. AIBN is commonly used as a radical initiator and as a foaming or blowing agent in plastics and rubber production. It is denser than water and moderately toxic if ingested. The compound is highly flammable, igniting readily from sparks or flames and burning intensely and persistently, producing toxic nitrogen oxides during combustion. AIBN is widely applied in catalysis, vinyl polymerizations, and as a foaming agent for plastic materials.

2,2'-Azobis(2-methylpropionitrile) CAS#78-67-1

Parameters

Melting point 102-104 °C (dec.)(lit.)
Boiling point 281.68°C (rough estimate)
density 1.11
vapor pressure 0.81Pa at 24.85℃
refractive index n20/D1.495
Fp 4℃
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
color Crystals from EtOH
Odorodorless
Water Solubility Insoluble
Merck 13920
BRN 1708400
Stability:Stability Flammable solid. Shock sensitive. Thermally unstable. May be explosive in combination with acetone or heptane. Incompatible with oxidizing agents.
InChIKeyOZAIFHULBGXAKX-VAWYXSNFSA-N
LogP1.1 at 25℃
CAS DataBase Reference78-67-1(CAS DataBase Reference)
NIST Chemistry Reference2,2'-Azo-bis-isobutyronitrile(78-67-1)
EPA Substance Registry SystemAzobis(isobutyronitrile) (78-67-1)

Safety Information

Hazard Codes E,Xn,F,Xi
Risk Statements 2-11-20/22-52/53-67-65-48/20-38-63-66-36
Safety Statements 39-41-47-61-62-36/37-16-26
RIDADR UN 3234 4.1
WGK Germany 2
RTECS UG0800000
4.4
HazardClass 4.1
PackingGroup II
HS Code 29269090
Hazardous Substances Data78-67-1(Hazardous Substances Data)
ToxicityLDLo orl-rat: 670 mg/kg 34ZIAG 0,117,69

2,2'-Azobis(2-methylpropionitrile) CAS#78-67-1

Product Application of 2,2'-Azobis(2-methylpropionitrile) CAS#78-67-1

2,2'-Azobis(2-methylpropionitrile) (AIBN) is widely used as an initiator in radical polymerization due to its ability to undergo homolytic cleavage and generate molecules with high activation energy. AIBN is the most commonly employed azo initiator, characterized by a relatively stable decomposition reaction that produces a single type of free radical with minimal induced decomposition. This property makes it particularly suitable for studying the kinetics of free radical polymerization.

2,2'-Azobis(2-methylpropionitrile) CAS#78-67-1

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